Critical Behavior of the Density of Binary Liquid Mixture Cyclohexane – Phenol
Publication Type
Conference Paper
Authors

-Abstract The dynamic shear viscosity coefficients of the binary liquid mixture cyclohexane-phenol for different phenol concentrations and temperatures are measured using glass capillary viscometer. Dynamic shear viscosity anomaly is observed near the critical temperature T_c =17.0℃ and the critical concentration of phenol x_c=2.70% by weight. Mode Coupling Theory is used to fit our experimental data above the critical temperature. It is found that the value of noncritical part of the dynamic shear viscosity η_0 = 0.8174 cP. The power law is expected for the mass density above critical temperature. The value of noncritical part of the mass density is found to be ρ_0= 0.7357 gm/cm^3 . The critical isobaric thermal expansion coefficient α_pc was calculated to be 1.66×〖10〗^(-6) ℃^(-1). The critical isobaric specific heat 〖 c〗_pc was found to be 106.6 Joule/(kg .K). Joule`s constant J was found to be 4.1180 Calorie/Joule and pressure derivation of the critical temperature 〖T_c〗^' was also calculated to be 1.22×〖10〗^(-4) ( K)/ Pa. 
Critical Behavior of the Density of Binary Liquid Mixture Cyclohexane – Phenol. Available from: 

Conference
Conference Title
The Eighth Palestinian International Chemistry Conference (PICC 2015) "Chemical Sciences Towards Knowledge Based Economy" At An Najah University, Nablus, Palestine
Conference Country
Palestine
Conference Date
April 22, 2015 - April 22, 2015
Conference Sponsor
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