Synthesis, spectra and X-ray crystallography of dipyridin-2-ylmethanone oxime and its CuX2(oxime)2 complexes: Thermal, Hirshfeld surface and DFT analysis
- Publication Type
- Original research
- Authors
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Dipyridin-2-ylmethanone oxime (C11H9N3O), was prepared using di-2-pyridyl ketone. The oxime ligand and its neutral CuX2 (oxime)2 (X = Cl or Br) complexes have been identified with the aid of several spectroscopic techniques such as: IR, EI-MS, EA, UV–visible, TG, 1H-NMR and finally the structure of the free oxime ligand was confirmed by X-ray diffractionstudies. The oxime crystallizes in the monoclinic space group P21/c, with cell parameters a = 8.8811 (8) Å, b = 10.6362 (8) Å, c = 11.2050 (8) Å, β = 109.085 (4) º, V = 1000.26 (14) Å3 and Z = 4. The molecular conformation is stabilized by a strong intramolecular OH⋯N hydrogen bonding between the hydroxyl group of the oxime moiety and the nitrogen of the pyridine ring.
Journal
- Title
- Journal of Molecular Structure
- Publisher
- ELSEVIER
- Publisher Country
- Netherlands
- Indexing
- Thomson Reuters
- Impact Factor
- 1.78
- Publication Type
- Prtinted only
- Volume
- 1154
- Year
- 2018
- Pages
- 619-625