Low Temperature Sintering and Dielectric Properties of (Ba,Ca)(Ti,Li)(O,F)3 Ceramics with High Permittivity
Publication Type
Original research
Authors
  • Hikmat S. Hilal
  • Laldja Taïbi-Benziada
  • Régnault Von Der Mühll

Cold-pressed pellets were prepared from a powder mixture of BaTiO3 with 5 mol% of (CaF2 + LiF). The pellets were then air-fired at different temperatures (800, 930, 1000 or 1100 °C) for different times (2, 4 or 8 h). Dielectric measurements were conducted at temperatures in the range 100–450 K with a wide frequency range, 100 Hz–40 MHz. Permittivity, View the MathML source, showed a diffuse ferroelectric–paraelectric phase transition at lower temperatures (263 Kless-than-or-equals, slantTCless-than-or-equals, slant368 K), where TC is the Curie temperature. In agreement with a non-relaxor ferroelectric behavior, the ferroelectric Curie temperature was frequency-independent. Dielectric dispersion was significant beyond not, vert, similar10 MHz. Ceramics sintered between 930 and 1100 °C are promising candidates for future fabrication of class II capacitors.

Low Temperature Sintering and Dielectric Properties of (Ba,Ca)(Ti,Li)(O,F)3 Ceramics with High Permittivity

Journal
Title
Solid State Sciences 8 (2006) 922–926
Publisher
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Publisher Country
Palestine
Publication Type
Both (Printed and Online)
Volume
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Year
2006
Pages
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