Design and characterization of poly (3-hydroxybutyrate-co-hydroxyhexanoate) nanoparticles and their grafting in whey protein-based nanocomposites
Publication Type
Original research
Authors

This work succeeded in the preparation of a nano-biocomposite material based on the use of poly-3-hydroxybutyrate-co-hydroxyhexanoate nanoparticles (PHBHHx-NPs) within a scaffold of whey protein (WP) based films. The experimental conditions for PHBHHx-NPs preparation by solvent-evaporation technique were set up, and the obtained NPs characterized. Dynamic light scattering analyses showed that PHBHHx-NPs are stable, exhibiting a zeta-potential value close to −40 mV and a Z-average size of 80 nm. Morphological characterization by transmission and scanning electron microscopy confirmed nanoparticle average dimensions. The addition of PHBHHx-NPs to WP-based films improved the mechanical properties of the derived bioplastics, producing more extensible materials preserving their mechanical resistance. The grafting of PHBHHx-NPs as material fillers also enhanced the film barrier properties towards O2, the permeability to both water vapor and CO2 remaining unaffected.

Journal
Title
Food Hydrocolloids
Publisher
Elsevier B.V
Publisher Country
Netherlands
Indexing
Scopus
Impact Factor
8.94
Publication Type
Prtinted only
Volume
110
Year
2020
Pages
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