X-Ray Single-Crystal Structure of a Novel Di-μ-Chloro-Bis[Chloro(2,9-Dimethyl-1,10-Phenanthroline)Nickel(II)] Complex: Synthesis, and Spectral and Thermal Studies
- Publication Type
- Original research
- Authors
- Ismail Warad
- Belkheir Hammouti
- Taibi Ben Hadda
- Ahmed Boshaala
- Salim F. Haddad
A binuclear nickel(II) chloride complex with dimethyl-1,10-phenanthroline, di-μ-chloro-bis[chloro(2,9-dimethyl-1,10-phenanthroline)nickel(II)] dimer, has been prepared and its molecular structure determined by X-ray diffraction. The crystal is triclinic, space group P−1, with the Ni(II) in [NiCl2(C14H12N2)]2 coordinated to two N of the phen ligand and three Cl−, one terminal and two bridging. A center of inversion lies midway between two Ni(II). Overall Ni(II) coordination is distorted triangular bipyramidal. The dimer complex was also characterized by elemental analysis, FAB-MS, IR and UV–visible spectroscopy, and thermogravimetric analysis.
Journal
- Title
- Research on Chemical Intermediates, DOI 10.1007/s11164-012-0917-y
- Publisher
- --
- Publisher Country
- Palestine
- Publication Type
- Both (Printed and Online)
- Volume
- --
- Year
- 2013
- Pages
- --