A new symmetric branched 4-nitrophenyl hydrazine compound has been prepared in one-step procedure by direct condensation of aromatic ketone with hydrazine in MeOH. The synthesized compound, red isomer, was characterized by IR, ¹H and ¹³C NMR spectroscopy, Elemental analyses, Mass spectrometry and X-ray crystallography. Refluxing in MeOH solution led to thermo-isomerism offering a white isomer product that was characterized by X-ray crystallography. The red isomer crystallizes in the orthorhombic system having space group Pbcn, with a = 12.7612(4), b = 11.5197(3), c = 20.1586(7) Å, V = 2963.42(16) Å ³, Z = 8 while the white isomer crystallizes in the triclinic system having space group P ^-1, with a = 7.8007(4), 8.5966(7), 12.224 (1) Å, α= 71.133(7), β= 81.281(5), γ= 74.895(5) ^°, V = 746.86(9) Å ³, Z = 2. Molecules of both compounds are twisted at N2-N3 bond with the C7-N2-N3-C9 torsion angle of 155.23(12) and -113.36(18) ^°, respectively. The crystal structures of both compounds are stabilized by weak intramolecular C - H ...N contacts and intermolecular C - H ...O hydrogen bonding interactions. In addition, π- π stacking interactions are observed between the same aromatic rings of molecules. © 2015 Indian Academy of Sciences.

العنوان

Journal of Chemical Sciences

الناشر

Springer India

بلد الناشر

الهند

Indexing

Thomson Reuters

معامل التأثير

1,254

نوع المنشور

مطبوع فقط

المجلد

127

السنة

2015

الصفحات

2211-2216