Three diamine-bis(diphenylphosphinobutane)ruthenium(II) complexes, isolated from the reaction of [Cl₂Ru(dppb)] with diamines viz., 2,2-dimethyl-1,3-diamnopropane, 1,2-diaminocyclohexane and 1,8-diaminonaphthalene are reported. The synthesized complexes have been characterized on the basis of various physico-chemical studies viz., EDX, IR, FAB-MS, UV/Vis, NMR, TG-DTG and EXAFS studies. ³¹P NMR investigations confirm that the complex 3 is in cis form while the complexes 1-2 appear in trans form. The structure of complex 3 has been additionally determined by single crystal X-ray diffraction showing solvated dichloromethane. Furthermore, complex 3 crystallizes as monoclinic unit cell with P2(1)/n space group. © 2014 Elsevier B.V. All rights reserved.

العنوان

Journal of Molecular Structure

الناشر

Elsevier

بلد الناشر

هولندا

Indexing

Thomson Reuters

معامل التأثير

2,011

نوع المنشور

مطبوع فقط

المجلد

1076

السنة

2014

الصفحات

724-729