Reactions of morpholine, piperidine and piperazine with Os(VIII) catalyzed hexacyanoferrate(III) in alkaline media to produce the corresponding lactam have been studied at constant temperature and ionic strength.. The reactions followed first order kinetics with respect to [amine] and [Os(VIII)] but were independent of [Fe(CN)₆^3-] and [OH^-]. The effects of introduced electrolytes, potassium hexacyanoferrate(II), relative permitivity and temperature have also been studied. A mechanism accounting for these results has been proposed.

العنوان

Latvian Institute of Organic Synthesis

الناشر

Khimiya Geterotsiklicheskikh Soedinenii

بلد الناشر

لاتفيا

نوع المنشور

مطبوع فقط

المجلد

2003

السنة

2003

الصفحات

559-565