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نوع المنشور

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المؤلفون

An aminopolycarboxylic acid chelating agent; tris(2-aminoethyl)aminehexaacetic acid (TAHA) was prepared and

characterized. TAHA formed stable complexes with Cu(II) ions and other metal ions at pH 10. The complexation behavior

was studied by spectrophotometry at the complex maximum wavelength. Mixtures of Cu(II) and other metal ions (M

;

, Co

, Ni

, Cd

)

were titrated with TAHA at pH 10. The stoichiometry of ligand - to - metal was found to be 1:1. The

stability constant of Cu(II)–TAHA complex was determined to be 1.86×10

by using the continuous variation method.

Beer’s law was obeyed over the concentration range 3.0×10

–4

M – 1.2×10

–2

M for Cu(II) solution. The results of the

quantitative determination of Cu(II) gave LOD and LOQ values of 7.285×10

–6

M and 2.428×10

–5

M respectively. The

percent relative standard deviation (%RSD) for five replicate samples was found to be 1.088% and 4.804% for Cu(II)

concentrations of 1.2×10

–2

M and 3.0×10

–4

M respectively

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