Three closely related (2E,200E)-3,300-(1,4-phenylene)- bis[1-(methoxyphenyl)prop-2-en-1-ones]: supramolecular assemblies in one dimension mediated by hydrogen bonding and C—H  p interactions
نوع المنشور
بحث أصيل
المؤلفون
النص الكامل
تحميل

In the title compounds, (2E,20E)-3,30-(1,4-phenylene)bis[1-(2-methoxyphenyl)-
prop-2-en-1-one], C26H22O4 (I), (2E,20E)-3,30-(1,4-phenylene)bis[1-(3-methoxyphenyl)
prop-2-en-1-one], C26H22O4 (II) and (2E,20E)-3,30-(1,4-phenylene)bis[1-
(3,4-dimethoxyphenyl)prop-2-en-1-one], C28H26O6 (III), the asymmetric unit
consists of a half-molecule, completed by crystallographic inversion symmetry.
The dihedral angles between the central and terminal benzene rings are
56.98 (8), 7.74 (7) and 7.73 (7) for (I), (II) and (III), respectively. In the crystal
of (I), molecules are linked by pairs of C—H   interactions into chains
running parallel to [101]. The packing for (II) and (III), features inversion
dimers linked by pairs of C—H  O hydrogen bonds, forming R2
2(16) and R2
2(14)
ring motifs, respectively, as parts of [201] and [101] chains, respectively.

المجلة
العنوان
Acta Crystallographica Section E: Crystallographic Communications
الناشر
International Union of Crystallography
بلد الناشر
فلسطين
Indexing
Scopus
معامل التأثير
None
نوع المنشور
مطبوع فقط
المجلد
73
السنة
2017
الصفحات
896-900