Synthesis, Characterization, Crystal Structure And Chemical Behavior of [1,1-Bis(Diphenylphosphinomethyl)Ethene]Ruthenium(II) Complex Toward Primary Alkylamine Addition
- نوع المنشور
- بحث أصيل
- المؤلفون
- Ismail Khalil Warad
- M. Rafiq H. Siddiqui
- Saud Al-Resayes
- Abdulrahman Al-Warthan
- Refaat Mahfouz
- النص الكامل
- تحميل
Reaction of the ruthenium phosphine complex [RuCl2(PPh3)3] 1 with an unsaturated functionalized diphosphine ligand, namely 1,1-bis(diphenyl-phosphinomethyl)ethene, H2C=C(CH2PPh2)2, (dppme) gave trans-Cl2Ru(dppme)2 2. Complex 2 served as a precursor for the synthesis of trans-Cl2Ru(dppme)(alkylamine)2 complexes 3–5 by reaction with RNH2. All these complexes were characterized by spectroscopic techniques and by elemental analysis. The solid-state structure of complex 2 was determined by X-ray crystallography.
المجلة
- العنوان
- Transition Metal Chemistry, Volume 34, Issue 3 , pp 347-352
- الناشر
- --
- بلد الناشر
- فلسطين
- نوع المنشور
- Both (Printed and Online)
- المجلد
- --
- السنة
- 2009
- الصفحات
- --