N-containing Organic compound As An Effective Corrosion Inhibitor For Copper In 2M HNO3: Weight Loss and Quantum Chemical Study
نوع المنشور
بحث أصيل
  • A. Zarrouk
  • B. Hammouti
  • H. Zarrok
  • I. Warad
  • M. Bouachrine
2Z)-1-(4-chlorophenyl)-2-[(3E)-3-[2-(4-chloropheny l)-2-oxoethylidene]-3,4dihydro quinoxalin- 2 (1H)-ylidene]ethanone (Q4) was tested as inhibito r for the corrosion of copper in 2M HNO 3 using gravimetric method at 303 – 343 K. The inhibi tor (Q4) showed about 90% inhibition efficiency (E (%)) at an optimum concentration of 1 0 -3 M. The inhibition efficiency increases with increase in inhibitor concentration but decrease wi th rise in temperature. Various parameters (Ea , ∆G ° ads , K ads ) for adsorption reveal a strong interaction betwee n inhibitor and copper surface. The negative values of ∆G° ads indicate the spontaneous adsorption of the inhibit or on copper surface. Kinetic parameters activation such as a E , aH °∆ , aS °∆ and pre-exponential factor have been calculated and discussed. Further, theore tical calculations were carried out and relations between computed parameters and experimen tal inhibition efficiency were discussed.
Scholars Research Library Der Pharma Chemica, 2011, 3 (5): 263-271
بلد الناشر
نوع المنشور
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