The catalytic properties of a simple iron-containing MOF based on fumaric acid, MIL-88A, were investigated in the ketalization of ethyl levulinate with glycerol. The corresponding product is a component of current interest as a renewable building block for many uses. Under the following conditions (solventless, 120 °C, stoichiometric ratio, 1% cat.), the reaction proceeds with good yields (85%), and the catalyst can be recovered and recycled without loss of activity, despite some changes in the crystalline lattice and morphology. Moreover, the residual iron content in the product is in the order of units of ppm (≤2), which demonstrates the robustness of the MOF under the reaction conditions.

العنوان

Maryam Hmoudah

الناشر

MDPI

بلد الناشر

إيطاليا

Indexing

Scopus

معامل التأثير

4,2

نوع المنشور

Both (Printed and Online)

المجلد

27

السنة

2022

الصفحات

7229