Neutral complex 1 and mono-cationic complex 2 were made available using Ph2PCH2CH2OCH3 and 1,2-diphenyl-1,2-ethanediamine ligands. One of the chloride atoms in complex 1 was abstracted by AgOTf to prepare the mono-cationic O–Ru–P closed complex 2. The hemilability of hybrid ether-phosphine ligand in such complexes was monitored by 31P{1H} NMR and confirmed by X-ray single crystal. XRD structure of complex 2 was found to be a Trigonal crystal system with P3 space group and Z = 6.

العنوان

Research on Chemical Intermediates March 2013, Volume 39, Issue 3, pp 1481-1490

الناشر

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بلد الناشر

فلسطين

نوع المنشور

Both (Printed and Online)

المجلد

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السنة

2013

الصفحات

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