One Step Synthesis of NiO Nanoparticles via Solid-state Thermal Decomposition at Low-Temperature of Novel Aqua dmphen-NiCl2 Complex
نوع المنشور
بحث أصيل
المؤلفون
  • Mohammed Suleiman
النص الكامل
تحميل
[NiCl2(C14H12N2)(H2O)] complex has been synthesized from nickel chloride hexahydrate (NiCl2·6H2O) and 2,9-dimethyl-1,10-phenanthroline (dmphen) as N,N-bidentate ligand. The synthesized complex was characterized by elemental analysis, infrared (IR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy and differential thermal/thermogravimetric analysis (TG/DTA). The complex was further confirmed by single crystal X-ray diffraction (XRD) as triclinic with space group P-1. The desired complex, subjected to thermal decomposition at low temperature of 400 °C in an open atmosphere, revealed a novel and facile synthesis of pure NiO nanoparticles with uniform spherical particle; the structure of the NiO nanoparticles product was elucidated on the basis of Fourier transform infrared (FT-IR), UV-vis spectroscopy, TG/DTA, XRD, scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDXS) and transmission electron microscopy (TEM).
المجلة
العنوان
International Journal of Molecular Sciences 14(12), 23941-23954
الناشر
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بلد الناشر
فلسطين
نوع المنشور
Both (Printed and Online)
المجلد
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السنة
2013
الصفحات
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